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Galvanic Bipolar Electrode Arrays with Self-Driven...
In Situ Confocal Fluorescence Lifetime Imaging of ...
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Electrochemiluminescence of dimethylaminonaphthalene-oxazaborine donor?acceptor luminophores
| Journal | Chemical Communications |
|---|---|
| Author | Kyoung-Rok Kim , Jiwoo Kim , Jinrok Oh , Joohoon Kim and Jong-In Hong |
| Citation | Chem. Commun., 2023, 59, 13058-13061 |
| DOI | http://10.1039/D3CC03892K |
Donor?acceptor (D?A) type molecules with a skeleton consisting of a dimethylaminonaphthalene donor and an oxazaborine acceptor were designed as efficient electrochemiluminescence (ECL) luminophores with tunable intramolecular charge transfer (ICT). The D?A ECL luminophores demonstrated that the ICT characteristics play a critical role in the electrochemistry and ECL of luminophores in the presence of tri-n-propylamine, which was rationalised experimentally and computationally. Furthemore, dual-peaked ECL-potential behaviours of the luminophores were rationalised using two competitive pathway ECL mechanisms, elucidated through the use of spooling ECL spectroscopy.
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Electrochemiluminescence of dimethylaminonaphthalene-oxazaborine donor?acceptor luminophores
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