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Electrochemical Functionalization of Single-Walled Carbon Nanotubes with Amine-Terminated Dendrimers Encapsulating Pt Nanoparticles: Toward Facile Field-Effect Transistor-Based Sensing Platforms

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Journal Sensors and Actuators, B: Chemical
Author Lee, Chang-Seuk; Ju, Youngwon; Kim, Joohoon; Kim, Tae Hyun
Citation Sensors and Actuators, B: Chemical Volume275 Pages367-372
DOI https://doi.org/10.1016/j.snb.2018.08.030
We present a method for functionalization of single-?walled carbon nanotubes (CNTs) with amine-?terminated dendrimers encapsulating catalytic nanoparticles, and demonstrate the feasibility of functionalized CNTs as efficient field-?effect transistor (FET)?-?sensing platforms.  As a model system, we synthesized Pt dendrimer-?encapsulated nanoparticles (DENs) using amine-?terminated sixth-?generation poly(amidoamine) dendrimers, and functionalized CNT-?based FET channels with Pt DENs via electro-?oxidative grafting of the terminal amines of dendrimers onto the surface of CNTs.  We also demonstrated spatially-?controlled surface functionalization of CNTs and subsequent modification of the functionalized CNT-?based FET channels with glutamate oxidases for efficient FET-?based sensing of glutamates.  Our approach could facilitate the functionalization of CNTs with a variety of catalytic nanoparticles and biol. active materials, enabling the development of sensitive and selective FET-?based sensor devices.

  1. Electrochemical Functionalization of Single-Walled Carbon Nanotubes with Amine-Terminated Dendrimers Encapsulating Pt Nanoparticles: Toward Facile Field-Effect Transistor-Based Sensing Platforms

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    Category2018 AuthorKayeong Shin, Jaeyeong Choi, Yeoju Kim, Yoonjeong Lee, Joohoon Kim, Seungho Lee,, Hoeil Chung JournalJournal of Chromatography A CitationJ .Chromatogr. A 1556(2018) 97?102 file
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