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Color-Tunable Electrogenerated Chemiluminescence of Ruthenium N-Heterocyclic Carbene Complexes

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Journal Electroanalysis
Author Hee-Jun Park, Sangwook Yoo, Ik-Soo Shin, Young Keun Chung,, Joohoon Kim
Citation 2013, 25, 5, 1111-1115
DOI http://dx.doi.org/10.1002/elan.201200619

Ru(II) complexes 1–3 bearing various N-heterocyclic carbene (NHC) ligands were synthesized, and their photophysical, electrochemical, and electrogenerated chemiluminescence (ECL) properties were discussed to evaluate a potential of their use as multicolor ECL labels. Interestingly, they exhibited ECL emission ranging from greenish-yellow to red both in nonaqueous and mixed aqueous solutions, which might show the potential of the Ru(II) complexes as multicolor ECL labels.


Keywords:

  • Electrogenerated chemiluminescence (ECL);
  • Ruthenium complex;
  • N-Heterocyclic carbene (NHC) ligands;
  • Green ECL emitter



  1. Hee-Jun Park1, 
  2. Sangwook Yoo2, 
  3. Ik-Soo Shin3, 
  4. Young Keun Chung1,*, 
  5. Joohoon Kim2,*
  1. 1

    Intelligent Textile System Research Center and Department of Chemistry, College of Natural Sciences, Seoul National University, Seoul 151–747, Korea

  2. 2

    Department of Chemistry, Research Institute for Basic Sciences, Kyung Hee University, Seoul 130–701, Korea

  3. 3

    Department of Chemistry, Soongsil University, Seoul 156–743, Korea

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